AN 20642. The selection of the correct autosampler vial type is vital to the success of analyzing pyrethroid pesticides at low levels. A method for the determination of pyrethroids at 0.10 ng/mL was developed using solid phase extraction (SPE) for pre-concentration with subsequent analysis by GC with PTV simulated on-column injection. Careful selection of the autosampler vial type was needed to minimize adsorption effects.