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Orbitrap_SciLib
Reputable Mentor II
Reputable Mentor II
Hardman M, Makarov AA.
Anal Chem. 2003 Apr 1;75(7):1699-705.
The orbitrap mass analyzer employs the trapping of pulsed ion beams in an electrostatic quadro-logarithmic field. This field is created between an axial central electrode and a coaxial outer electrode. Stable ion trajectories combine rotation around the central electrode with harmonic oscillations along it. The frequencies of axial oscillations and hence mass-to-charge ratios of ions are obtained using fast Fourier transform of the image current detected on the two split halves of the outer electrode. This work proves that such a trap could be coupled to a continuous, electrospray, ion source. Such a coupling necessitated the development of an rf-only quadrupole for external accumulation of ions and their injection in very short (<1 µs) ion bunches. Along with good sensitivity, this mass spectrometer provides mass resolving power up to 150000 fwhm, mass accuracies within a few parts per million, and relative mass range up to 8-fold. The maximum number of ions available for analysis is limited by the space-charge capacity of the accumulation quadrupole.

http://pubs.acs.org/doi/pdf/10.1021/ac0258047
Thermo Masslab Ltd., Crewe Road, Wythenshawe, Manchester, M23 9BE, U.K.
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‎05-01-2012 10:37 AM
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